Mechanistic studies on the photochromism of [e]-annelated dimethyldihydropyrenes.
نویسندگان
چکیده
The photochemistry of several photochromic arene [e]-annelated dimethyldihydropyrenes (DHPs) was studied. These compounds have much larger photochemical ring opening quantum yields than the simple DHPs, making them potentially more useful as building blocks for photoswitchable materials.
منابع مشابه
A photochromic and thermochromic fluorescent protein
Photochromism is a change of colour induced by irradiation with light, while thermochromism is a change of colour due to a change of temperature. Both photochromism and thermochromism have been observed in inorganic and organic compounds, however thermochromism is much less common in biological systems. One mechanism by which molecular photochromism can occur is a photo-induced isomerization to...
متن کاملKinetic Aspects of Tetrahydrobenzo[b]pyran Formation in the Presence of Fructose as a Green Catalyst: a Mechanistic Investigation
The kinetics and mechanism of the reaction between benzaldehyde 1, malononitrile 2 and dimedone 3 in a mixture of ethanol and water as solvents in the presence of fructose as a biodegradable catalyst has been studied by the spectroscopic method (UV-Vis spectrophotometry method). The influence of various parameters (temperature, solvent and concentration) was studied on the reaction by means of ...
متن کاملPhotochromism in composite and hybrid materials based on transition-metal oxides and polyoxometalates
Photochromic materials are attractive and promising for applications in many fields. One subject in this area is to prepare and study the photochromism in composite or hybrid materials based on transition-metal oxides or polyoxometalates. Their properties not depend only on the chemical nature of each component, but also on the interface and synergy between them. Since the charge transfer plays...
متن کاملO7: The Mechanistic Role of Sleep in Posttraumatic Stress Disorder
Around 75% of civilians have experienced at least one traumatic event in their lives, and this number is considerably higher in many parts of the world, as well as in military veterans and first responders. Of those exposed to trauma, 15-25% will develop Posttraumatic Stress Disorder (PTSD). PTSD extracts enormous economic, health, and quality of life cost. Thus, it is critical to underst...
متن کاملPlatinum-oxygen Bond Formation: Kinetic and Mechanistic Studies
Reaction of [PtMe(C^N)(SMe2)] (C^N = 2-phenylpyridinate (ppy); 1a, C^N = benzo[h]quinolate, (bhq); 1b) with hydrogen peroxide gives the platinum(IV) complexes trans-[PtMe(OH)2(C^N)(H2O)] (C^N = ppy; 3a, C^N = bhq, 3b) bearing platinum-oxygen bonds. The Pt(II) complexes 1a and 1b have 5dπ(Pt)→π*(C^N) MLCT band in the visible region which is used to easily follow the kinetic of its reaction with ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
دوره 2 2 شماره
صفحات -
تاریخ انتشار 2003